Corrosion Behavior of Ternary Zr-25Ti-5Sn Alloy Doped with Ge as Biomaterials Implant in Simulation Body Fluid Solution
DOI:
https://doi.org/10.21776/MECHTA.2020.001.02.4Keywords:
Corrosion, Biomaterial, Metal Alloy, Terner Zr-25Ti-5SnAbstract
Corrosion research of metal alloys of Zr-25Ti-5Sn and Zr-25Ti-3Sn-2Geas biomaterials has been carried out in fluid solution. Zr-25Ti-5Snalloy is a ternary metal alloy developed for hard tissue biomaterials. Zr-25Ti-5Sn and Zr-25Ti-3Sn-2Ge alloys is melted in electric arc furnace. After being melted Zr-25Ti-5Sn and Zr-25Ti-3Sn-2Ge were characterized by optical microscopy. Hardness testing was carried out by the hardness microvickers method to determine the effect of germanium addition on Zr-25Ti-5Sn alloys. Corrosion testing of ternary metal alloys Zr-25Ti-5Sn and Zr-25Ti-3Sn-2Ge was carried out by the Tafel polarization method using three electrode systems. From the results of microstructure examination with optical microscope, the microstructure found in the ternary metal alloy Zr-25Ti-5Sn and Zr-25Ti-3Sn-2Ge are parallel plates and dendritic. The hardness test results show that the addition of germanium to the Zr-25Ti-5Sn ternary alloy increased the hardness of the alloy. Corrosion test results on ternary alloy Zr-25Ti-5Sn and Zr-25Ti-3Sn-2Geindicated that corrosion resistance of Zr-25Ti-5Snincreased when no addition of Germanium to Zr-25Ti-5Snalloy.
References
IMAI, KAZUHIRO., “In Vivo Investigation of Zr-Based Bulk Metallic Glasses Sub-Periosteally Implanted on the Bone Surfaceâ€, Journal of Materials Science and Chemical Engineering, v. 4, pp. 46-51, Jan. 2016.
ZHAO, GUO-HUA., ANUE, RAGNHILD E., MAO, HUAHAI., “Degradation of Zr-based bulk metallic glasses used in load-bearing implants: A tribocorrosion appraisalâ€, Journal of the Mechanical Behavior of Biomedical Materials, v. 12, n. 24, Dec. 2015.
HUANG, LU., PU, CHAO., FISHER, RICHARD K., et al., “A Zr-based bulk metallic glass for future stent applications: Materials properties, finite element modeling, and in vitro human vascular cell responseâ€, Journal of Acta Biomaterialia, Jul. 1996.
CORREA, DIEGO RAFAEL NESPEQUE., VICENTE, FÃBIO BOSSOI., ARAÚJO, RAUL OLIVEIRA., et al., “Effect of the substitutional elements on the microstructure of the Ti-15Mo-Zr and Ti-15Zr-Mo systems alloysâ€, Journal of Materials research technology, v. 4, n. 2, pp. 180-185, Marc. 2015.
GUAN, BAORU., SHI, XUETAO., DAN, ZHENHUA., et al., “Corrosion behavior, mechanical properties and cell cytotoxity of Zr-based bulk metallic glassesâ€, Journal of Intermetallics, v. 72, pp. 69-75, Feb. 2016.
SHI, Y.D., WANG, L.N., LIANG, Q. ZHOU., et al., “A high Zr-containing Ti-based alloy with ultralow Young's modulus and ultrahigh strength and elastic admissible strainâ€, Journal of Materials Science & Engineering A, v. 674, pp. 696-700, Aug. 2016.
HUA, NENGBIN., CHEN, WENZHE., WANG, WEIGUO., et al., “Tribological behavior of a Ni-free Zr-based bulk metallic glass with potential for biomedical applicationsâ€, Journal of Materials Science & Engineering C, v. 4, Apr. 2016.
PRASTIKA, VITA YULIANA., AMBARDI, PRADOTO., PRAJITNO, DJOKO HADI., “CORROSION BEHAVIOR OF Zr-10Mo ALLOYS INNIOBIUM-DOPED LACTATE RINGER’S SOLUTIONâ€,
Indonesian Material Science Journal, v. 20, n. 4, jul, 2019.
KUBIES, D., HIMMLOVA, L., RIEDEL, T., et al., “The Effect of Physicochemical Surface Properties of Implant Materialsâ€, v. 60, pp. 60-95, may. 2010.
AKIMOTO, TEISUKE., UENO, TAKESHI., TSUTSUMI, YUSUKE., et al“Evaluation of corrosion resistance of implant-use Ti-Zr binary alloyswith a range of compositions†Journal of biomedical materials research, 2016.
BJURSTE, L.M., . EMANUELSSON, L., ERISCON, , L.E., et al “Method for ultrastructural studies of the intact tissue-metal interfaceâ€, Journal of biomaterials, v. 11, octo. 1990.
HAO, Y.L., LI,S.J., SUN,S.Y., YANG, R., “Effect of Zr and Sn on Young’s modulus and superelasticityof Ti–Nb-based alloysâ€, Journal of Materials Science and Engineering, v. 441, pp 112-118, sept. 2006.
HORTON, J. A., PARSEL, D.E., “Biomedical Potential of a Zirconium-Based Bulk Metallic Glassâ€, Journal of Materials Research Society, v. 754, 2003.
OLIVEIRA, NILSON T. C., BIAGGIO, SONIA R., ROCHA-FILHO, ROMEU C., “Studies on the Stability of Anodic Oxides on Zirconium Biocompatible Alloys†Journal of . Braz. Chem. Soc, v.13, n. 4, pp. 463-468. 2002.
PULEO, DAVID A., HOLLERAN, LISA A., DOREMUS, ROBERT H., et al., “Osteoblast responses to orthopedic implant materials in vitroâ€, Journal of Biomedical Materials Research, v. 25, pp. 711-723, 1991.
ROSALBINO, F., MACCIO, D., SCAVINO, G., et al., “Corrosion behavior of new ternary zirconium alloys asalternative materials for biomedical applicationsâ€, Journal of Materials and Corrosion, v. 66, n. 10, 2015.
BRANZOI, IOAN VIOREL., IORDOC, MIHAI., CODESCU, MIRELA., “Electrochemical studies on the stability andcorrosion resistance of new zirconium-basedalloys for biomedical applicationsâ€, Journal of surface and interface analysisâ€, v. 40, pp. 167-173, dec. 2008.
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