PYROLYSIS OF CORN COB BIOMASS TOWARD GASEOUS PRODUCTS ON SMALL CAPACITY REACTOR
DOI:
https://doi.org/10.21776/MECHTA.2024.005.01.9Keywords:
Pyrolysis, Biomass, Corn Cab, Syngas, BentoniteAbstract
Corn waste is the result of agricultural production that can be further utilized and get additional economic for the community. Waste Corn cab is one of Indonesia abundant biomass apart from. The utilization of biomass by implementing pyrolysis process can be viable solution. This study aims to observe the determination corn cab pyrolysis using HCL-bentonite activation and without bentonite towards syngas product (CH4-H2-CO-CO2). Updraft reactor was utilized for 30 minutes pyrolysis process. We used MQ4, MQ8, MQ7 coupled with Arduino UNO for measuring CH4, H2, CO2 and CO in ppm unit. Compared without bentonite, the result showed that methane (CH4) gas production increased. In addition, we found also that hydrogen (H2) gas increased respectively. Not mention, the content of CO increased.
References
F. R. Baskoro, K. Takahashi, K. Morikawa, and K. Nagasawa, “Multi-objective optimization on total cost and carbon dioxide emission of coal supply for coal-fired power plants in Indonesia,” Socio-Economic Planning Sciences, vol. 81, no. March 2021, p. 101185, 2022, doi: 10.1016/j.seps.2021.101185.
Z. Liu, H. B. Saydaliev, J. Lan, S. Ali, and M. K. Anser, “Assessing the effectiveness of biomass energy in mitigating CO2 emissions: Evidence from Top-10 biomass energy consumer countries,” Renewable Energy, vol. 191, pp. 842–851, 2022, doi: 10.1016/j.renene.2022.03.053.
N. Bilandzija et al., “Evaluation of Croatian agricultural solid biomass energy potential,” Renewable and Sustainable Energy Reviews, vol. 93, no. December 2017, pp. 225–230, 2018, doi: 10.1016/j.rser.2018.05.040.
M. Jahangiri, R. A. Rizi, and A. A. Shamsabadi, “Feasibility study on simultaneous generation of electricity and heat using renewable energies in Zarrin Shahr, Iran,” Sustainable Cities and Society, vol. 38, no. February, pp. 647–661, 2018, doi: 10.1016/j.scs.2018.01.043.
A. Schaffartzik, A. Brad, and M. Pichler, “A world away and close to home: The multi-scalar ‘making of’ Indonesia’s energy landscape,” Energy Policy, vol. 109, no. June, pp. 817–824, 2017, doi: 10.1016/j.enpol.2017.06.045.
E. HAMBALI, F. N. NISYA, A. THAHAR, A. NURYANTI, and H. WIJAYA, “Potential of Biomass as Bioenergy Feedstock in Indonesia,” Journal of the Japan Institute of Energy, vol. 95, no. 8, pp. 629–638, 2016, doi: 10.3775/jie.95.629.
Z. T. Yu, X. Xu, Y. C. Hu, L. W. Fan, and K. F. Cen, “Prediction of higher heating values of biomass from proximate and ultimate analyses,” Fuel, vol. 90, no. 3, pp. 1128–1132, 2011, doi: 10.1016/j.fuel.2010.11.031.
Y. Kar, “Catalytic cracking of pyrolytic oil by using bentonite clay for green liquid hydrocarbon fuels production,” Biomass and Bioenergy, vol. 119, no. April, pp. 473–479, 2018, doi: 10.1016/j.biombioe.2018.10.014.
M. Karod, Z. A. Pollard, M. T. Ahmad, G. Dou, L. Gao, and J. L. Goldfarb, “Impact of Bentonite Clay on In Situ Pyrolysis vs. Hydrothermal Carbonization of Avocado Pit Biomass,” Catalysts, vol. 12, no. 6, 2022, doi: 10.3390/catal12060655.
T. Suprianto, Winarto, W. Wijayanti, and I. N. G. Wardana, “Synergistic effect of curcumin and activated carbon catalyst enhancing hydrogen production from biomass pyrolysis,” International Journal of Hydrogen Energy, vol. 46, no. 10, pp. 7147–7164, 2021, doi: 10.1016/j.ijhydene.2020.11.211.
T. Suprianto, Winarto, W. Wijayanti, and I. Wardana, “Effect of activated carbon catalyst on the cracking of biomass molecules into light hydrocarbons in biomass pyrolysis,” IOP Conference Series: Materials Science and Engineering, vol. 1034, no. 1, p. 012079, 2021, doi: 10.1088/1757-899x/1034/1/012079.
S. Wang, G. Dai, H. Yang, and Z. Luo, “Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review,” Progress in Energy and Combustion Science, vol. 62, pp. 33–86, 2017, doi: 10.1016/j.pecs.2017.05.004.
I. Nurika, A. Rahmadhanti, and S. Suhartini, “Bioconversion of lignin and methane production from Corn cobs (Zea mays) treated by lignin-degrading bacteria,” IOP Conference Series: Earth and Environmental Science, vol. 924, no. 1, 2021, doi: 10.1088/1755-1315/924/1/012072.
H. Yang, R. Yan, H. Chen, D. H. Lee, and C. Zheng, “Characteristics of hemicellulose, cellulose and lignin pyrolysis,” Fuel, vol. 86, no. 12–13, pp. 1781–1788, 2007, doi: 10.1016/j.fuel.2006.12.013.
A. Maged, S. Kharbish, I. S. Ismael, and A. Bhatnagar, “Characterization of activated bentonite clay mineral and the mechanisms underlying its sorption for ciprofloxacin from aqueous solution,” Environmental Science and Pollution Research, vol. 27, no. 26, pp. 32980–32997, 2020, doi: 10.1007/s11356-020-09267-1.
H. Bu et al., “Effects of complexation between organic matter (OM) and clay mineral on OM pyrolysis,” Geochimica et Cosmochimica Acta, vol. 212, pp. 1–15, 2017, doi: 10.1016/j.gca.2017.04.045.
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Copyright (c) 2024 Fisal Yuliansyah, Nurkholis Hamidi, Mega Nur Sasongko
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